Information card for entry 1576405

Structure parameters

• Formula: C37.5 H53.74 Cl3 F3 N7.75 O3.25 Rh2 S
• Calculated formula: C37.478 H53.673 Cl3 F3 N7.761 O3.239 Rh2 S
• Title of publication: Low-oxidation state dirhodium complex produced by four-electron reduction of dirhodium(ii) complex supported by a flexible macrocyclic ligand
• Authors of publication: Yan, Liping; Moriyama, Takumi; Akita, Yutaro; Muratsugu, Satoshi; Tada, Mizuki; Yamashita, Makoto; Morimoto, Yuma
• Journal of publication: Chemical Science
• Year of publication: 2026
• a: 17.9664 ± 0.0004 Å
• b: 15.6304 ± 0.0003 Å
• c: 16.1234 ± 0.0003 Å
• α: 90°
• β: 98.88 ± 0.002°
• γ: 90°
• Cell volume: 4473.53 ± 0.16 ų
• Cell temperature: 93 ± 2 K
• Ambient diffraction temperature: 93 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0555
• Residual factor for significantly intense reflections: 0.0508
• Weighted residual factors for significantly intense reflections: 0.1198
• Weighted residual factors for all reflections included in the refinement: 0.1212
• Goodness-of-fit parameter for all reflections included in the refinement: 1.274
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No