Information card for entry 1576406

Structure parameters

• Formula: C48 H64 F12 N12 O12 Rh2 S4
• Calculated formula: C48 H64 F12 N12 O12 Rh2 S4
• Title of publication: Low-oxidation state dirhodium complex produced by four-electron reduction of dirhodium(ii) complex supported by a flexible macrocyclic ligand
• Authors of publication: Yan, Liping; Moriyama, Takumi; Akita, Yutaro; Muratsugu, Satoshi; Tada, Mizuki; Yamashita, Makoto; Morimoto, Yuma
• Journal of publication: Chemical Science
• Year of publication: 2026
• a: 11.588 ± 0.0003 Å
• b: 20.6879 ± 0.0007 Å
• c: 27.049 ± 0.0008 Å
• α: 90°
• β: 102.188 ± 0.003°
• γ: 90°
• Cell volume: 6338.3 ± 0.3 ų
• Cell temperature: 93 ± 2 K
• Ambient diffraction temperature: 93 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0721
• Residual factor for significantly intense reflections: 0.0566
• Weighted residual factors for significantly intense reflections: 0.1229
• Weighted residual factors for all reflections included in the refinement: 0.1286
• Goodness-of-fit parameter for all reflections included in the refinement: 1.101
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No