Information card for entry 1577010

Structure parameters

• Formula: C49 H38 Cl5 N2 O2 Rh
• Calculated formula: C49 H38 Cl5 N2 O2 Rh
• Title of publication: Achieving (quasi)-monocoordination in metal complexes with an exceptionally bulky carbene ligand.
• Authors of publication: Zapf, Ludwig; Rivard, Eric
• Journal of publication: Chemical science
• Year of publication: 2026
• Journal volume: 17
• Journal issue: 13
• Pages of publication: 6500 - 6506
• a: 10.2314 ± 0.0003 Å
• b: 12.158 ± 0.0004 Å
• c: 17.7859 ± 0.0006 Å
• α: 96.123 ± 0.002°
• β: 101.349 ± 0.001°
• γ: 96.337 ± 0.002°
• Cell volume: 2137.14 ± 0.12 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0507
• Residual factor for significantly intense reflections: 0.0393
• Weighted residual factors for significantly intense reflections: 0.0831
• Weighted residual factors for all reflections included in the refinement: 0.09
• Goodness-of-fit parameter for all reflections included in the refinement: 1.093
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Diffraction radiation X-ray symbol: K-L~2,3~
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No