Information card for entry 1577101

Structure parameters

• Formula: C18 H40 Cl2 P4 Pt2 Si
• Calculated formula: C18 H40 Cl2 P4 Pt2 Si
• Title of publication: Cooperative reactivity of halomethanes and -silanes at an A-frame complex: transannular addition versus bridging tetrylenes
• Authors of publication: Passargus, Max; Nieuwland, Celine; Arrowsmith, Merle; Bickelhaupt, F. Matthias; Braunschweig, Holger
• Journal of publication: Chemical Science
• Year of publication: 2026
• a: 9.639 ± 0.004 Å
• b: 29.672 ± 0.011 Å
• c: 9.783 ± 0.004 Å
• α: 90°
• β: 94.077 ± 0.013°
• γ: 90°
• Cell volume: 2790.9 ± 1.9 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0416
• Residual factor for significantly intense reflections: 0.0329
• Weighted residual factors for significantly intense reflections: 0.0697
• Weighted residual factors for all reflections included in the refinement: 0.074
• Goodness-of-fit parameter for all reflections included in the refinement: 1.046
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Diffraction radiation X-ray symbol: K-L~2,3~
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No