Information card for entry 1577102

Structure parameters

• Formula: C13 H31 Cl4 P4 Pt2 Si
• Calculated formula: C13 H31 Cl4 P4 Pt2 Si
• Title of publication: Cooperative reactivity of halomethanes and -silanes at an A-frame complex: transannular addition versus bridging tetrylenes
• Authors of publication: Passargus, Max; Nieuwland, Celine; Arrowsmith, Merle; Bickelhaupt, F. Matthias; Braunschweig, Holger
• Journal of publication: Chemical Science
• Year of publication: 2026
• a: 16.205 ± 0.003 Å
• b: 12.4401 ± 0.0017 Å
• c: 12.88 ± 0.003 Å
• α: 90°
• β: 103.351 ± 0.009°
• γ: 90°
• Cell volume: 2526.3 ± 0.8 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0318
• Residual factor for significantly intense reflections: 0.0294
• Weighted residual factors for significantly intense reflections: 0.0736
• Weighted residual factors for all reflections included in the refinement: 0.0752
• Goodness-of-fit parameter for all reflections included in the refinement: 1.077
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Diffraction radiation X-ray symbol: K-L~2,3~
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No