Information card for entry 1577103

Structure parameters

• Formula: C13.5 H35 Br3 Cl3 P4 Pt2 Si a an e ed ez ha lf nt pe sq ue
• Calculated formula: C8.25 H22.5 Br2.25 Cl2.25 P3 Pt1.5 Si0.75
• Title of publication: Cooperative reactivity of halomethanes and -silanes at an A-frame complex: transannular addition versus bridging tetrylenes
• Authors of publication: Passargus, Max; Nieuwland, Celine; Arrowsmith, Merle; Bickelhaupt, F. Matthias; Braunschweig, Holger
• Journal of publication: Chemical Science
• Year of publication: 2026
• a: 36.193 ± 0.0009 Å
• b: 36.193 ± 0.0009 Å
• c: 11.8809 ± 0.0005 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 13478.1 ± 0.7 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 18
• Space group number: 148
• Hermann-Mauguin space group symbol: R -3 :H
• Hall space group symbol: -R 3
• Residual factor for all reflections: 0.0458
• Residual factor for significantly intense reflections: 0.0331
• Weighted residual factors for significantly intense reflections: 0.067
• Weighted residual factors for all reflections included in the refinement: 0.0709
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Diffraction radiation X-ray symbol: K-L~2,3~
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No