Information card for entry 4035684

Structure parameters

• Formula: C22 H36 O3 Si
• Calculated formula: C22 H36 O3 Si
• SMILES: [Si](O[C@H]1C(=O)O[C@H]([C@@H](CC1)C)c1ccccc1)(C(C)C)(C(C)C)C(C)C.[Si](O[C@@H]1C(=O)O[C@@H]([C@H](CC1)C)c1ccccc1)(C(C)C)(C(C)C)C(C)C
• Title of publication: Acyclic Remote 1,5- and 1,4,5-Stereocontrol in the Catalytic Stereoselective Reactions of β-Lactams with Aldehydes: The Effect of the N-Methylimidazole Ligand.
• Authors of publication: Plata, Paulina; Klimczak, Urszula; Zambroń, Bartosz K
• Journal of publication: The Journal of organic chemistry
• Year of publication: 2018
• Journal volume: 83
• Journal issue: 23
• Pages of publication: 14527 - 14552
• a: 19.206 ± 0.003 Å
• b: 11.2062 ± 0.0016 Å
• c: 10.5976 ± 0.0015 Å
• α: 90°
• β: 92.178 ± 0.008°
• γ: 90°
• Cell volume: 2279.2 ± 0.6 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0852
• Residual factor for significantly intense reflections: 0.0689
• Weighted residual factors for significantly intense reflections: 0.2031
• Weighted residual factors for all reflections included in the refinement: 0.2276
• Goodness-of-fit parameter for all reflections included in the refinement: 1.026
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No