Group 1 Bis(iminophosphorano)methanides, Part 1:N-Alkyl and Silyl Derivatives of the Sterically Demanding Methanes H2C(PPh2NR)2(R = Adamantyl and Trimethylsilyl)
Authors of publication
Wooles, Ashley J.; Gregson, Matthew; Cooper, Oliver J.; Middleton-Gear, Amy; Mills, David P.; Lewis, William; Blake, Alexander J.; Liddle, Stephen T.
Journal of publication
Organometallics
Year of publication
2011
Journal volume
30
Journal issue
20
Pages of publication
5314
a
10.5879 ± 0.0011 Å
b
11.1951 ± 0.0012 Å
c
16.342 ± 0.0012 Å
α
107.63 ± 0.008°
β
102.177 ± 0.008°
γ
92.073 ± 0.009°
Cell volume
1794.1 ± 0.3 Å3
Cell temperature
90 ± 2 K
Ambient diffraction temperature
90 ± 2 K
Number of distinct elements
4
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0596
Residual factor for significantly intense reflections
0.0511
Weighted residual factors for significantly intense reflections
0.136
Weighted residual factors for all reflections included in the refinement
0.145
Goodness-of-fit parameter for all reflections included in the refinement
