Information card for entry 4066349

Structure parameters

• Formula: C21 H37 Rh Si
• Calculated formula: C21 H37 Rh Si
• SMILES: [Rh]1234567([c]8([c]4([c]3([c]2([c]18C)C)C)C)[Si](C(C)(C)C)(C)C)[CH2]=[C]5([C]6(=[CH2]7)C)C
• Title of publication: Synthesis of Rhodium Complexes with Bulky Substituted Cyclopentadienyl Ligands. H/D Exchange Reactions and Silane Activation†
• Authors of publication: Esqueda, Ana Cristina; Conejero, Salvador; Maya, Celia; Carmona, Ernesto
• Journal of publication: Organometallics
• Year of publication: 2010
• Journal volume: 29
• Journal issue: 21
• Pages of publication: 5481
• a: 8.8037 ± 0.0006 Å
• b: 9.6272 ± 0.0006 Å
• c: 13.0123 ± 0.0008 Å
• α: 79.33 ± 0.003°
• β: 81.354 ± 0.003°
• γ: 82.559 ± 0.003°
• Cell volume: 1065.59 ± 0.12 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0453
• Residual factor for significantly intense reflections: 0.042
• Weighted residual factors for significantly intense reflections: 0.112
• Weighted residual factors for all reflections included in the refinement: 0.1143
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No