Information card for entry 4067942

Structure parameters

• Formula: C37 H62 Au2 Cl2 F12 P2 Sb2
• Calculated formula: C37 H62 Au2 Cl2 F12 P2 Sb2
• SMILES: [Au]1([P](C(C)(C)C)(C(C)(C)C)c2ccccc2c2c([P]([Au]3[CH2]=[C]3(C)C)(C(C)(C)C)C(C)(C)C)cccc2)[CH2]=[C]1(C)C.[Sb](F)(F)(F)(F)([F-])F.[Sb](F)(F)(F)(F)(F)[F-].C(Cl)Cl
• Title of publication: Synthesis and Structure of Dicationic, Bis(gold) π-Alkene Complexes Containing a 2,2′-Bis(phosphino)biphenyl Ligand
• Authors of publication: Brooner, Rachel E. M.; Widenhoefer, Ross A.
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 2
• Pages of publication: 768
• a: 13.761 ± 0.0004 Å
• b: 17.2858 ± 0.0005 Å
• c: 39.9274 ± 0.0012 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 9497.5 ± 0.5 ų
• Cell temperature: 110 K
• Ambient diffraction temperature: 110 K
• Number of distinct elements: 7
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0918
• Residual factor for significantly intense reflections: 0.0529
• Weighted residual factors for significantly intense reflections: 0.1268
• Weighted residual factors for all reflections included in the refinement: 0.1453
• Goodness-of-fit parameter for all reflections included in the refinement: 1.085
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No