Information card for entry 4067943

Structure parameters

• Formula: C39 H65 Au2 Cl2 F12 P2 Sb2
• Calculated formula: C39 H65 Au2 Cl2 F12 P2 Sb2
• SMILES: [Au]1([P](C(C)(C)C)(C(C)(C)C)c2ccccc2c2ccccc2[P]([Au]2[CH2]=[CH]2CCC)(C(C)(C)C)C(C)(C)C)[CH2]=[CH]1CCC.[Sb](F)(F)(F)(F)(F)[F-].[Sb](F)(F)(F)(F)([F-])F.C(Cl)Cl
• Title of publication: Synthesis and Structure of Dicationic, Bis(gold) π-Alkene Complexes Containing a 2,2′-Bis(phosphino)biphenyl Ligand
• Authors of publication: Brooner, Rachel E. M.; Widenhoefer, Ross A.
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 2
• Pages of publication: 768
• a: 19.0763 ± 0.0006 Å
• b: 15.7558 ± 0.0005 Å
• c: 16.9063 ± 0.0005 Å
• α: 90°
• β: 93.1807 ± 0.0018°
• γ: 90°
• Cell volume: 5073.6 ± 0.3 ų
• Cell temperature: 110 K
• Ambient diffraction temperature: 110 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1178
• Residual factor for significantly intense reflections: 0.0716
• Weighted residual factors for significantly intense reflections: 0.1693
• Weighted residual factors for all reflections included in the refinement: 0.1817
• Goodness-of-fit parameter for all reflections included in the refinement: 1.075
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No