Information card for entry 4068281

Structure parameters

• Formula: C51 H72 N2 O P2 Rh2 Si2
• Calculated formula: C51 H72 N2 O P2 Rh2 Si2
• SMILES: [Rh]1234(N(P(=[C]51[Rh]167([N](=P5(c5ccccc5)c5ccccc5)[Si](C)(C)C)[CH]5=[CH]1CC[CH]6=[CH]7CC5)(c1ccccc1)c1ccccc1)[Si](C)(C)C)[CH]1=[CH]2CC[CH]3=[CH]4CC1.O(CC)CC
• Title of publication: Bimetallic, Spirocyclic, Methylene-Bridged Carbene Complexes of Rhodium and Palladium Derived by Stepwise Metalations of Lithiated Bis(diphenylphosphoranotrimethylsilylimido)methandiide
• Authors of publication: Fang, Min; Jones, Nathan D.; Friesen, Kristina; Lin, Guanyang; Ferguson, Michael J.; McDonald, Robert; Lukowski, Robert; Cavell, Ronald G.
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 6
• Pages of publication: 1652
• a: 11.4079 ± 0.0008 Å
• b: 32.683 ± 0.002 Å
• c: 13.8489 ± 0.001 Å
• α: 90°
• β: 104.706 ± 0.001°
• γ: 90°
• Cell volume: 4994.3 ± 0.6 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0351
• Residual factor for significantly intense reflections: 0.0284
• Weighted residual factors for significantly intense reflections: 0.0709
• Weighted residual factors for all reflections included in the refinement: 0.0781
• Goodness-of-fit parameter for all reflections included in the refinement: 1.093
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No