Information card for entry 4068282

Structure parameters

• Formula: C36 H43 N2 O2 P2 Pd Rh Si2
• Calculated formula: C36 H43 N2 O2 P2 Pd Rh Si2
• SMILES: [Pd]123([N](=P(C43[Rh]([N](=P4(c3ccccc3)c3ccccc3)[Si](C)(C)C)(C#[O])C#[O])(c3ccccc3)c3ccccc3)[Si](C)(C)C)[CH2]=[CH]1C2
• Title of publication: Bimetallic, Spirocyclic, Methylene-Bridged Carbene Complexes of Rhodium and Palladium Derived by Stepwise Metalations of Lithiated Bis(diphenylphosphoranotrimethylsilylimido)methandiide
• Authors of publication: Fang, Min; Jones, Nathan D.; Friesen, Kristina; Lin, Guanyang; Ferguson, Michael J.; McDonald, Robert; Lukowski, Robert; Cavell, Ronald G.
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 6
• Pages of publication: 1652
• a: 19.741 ± 0.0016 Å
• b: 18.8899 ± 0.0016 Å
• c: 20.6055 ± 0.0017 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 7683.9 ± 1.1 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 8
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0631
• Residual factor for significantly intense reflections: 0.0336
• Weighted residual factors for significantly intense reflections: 0.069
• Weighted residual factors for all reflections included in the refinement: 0.08
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No