Information card for entry 4068283

Structure parameters

• Formula: C35 H38 N2 O4 P2 Rh2 Si2
• Calculated formula: C35 H38 N2 O4 P2 Rh2 Si2
• SMILES: [Rh]1([N](=P(C21[Rh]([N](=P2(c1ccccc1)c1ccccc1)[Si](C)(C)C)(C#[O])C#[O])(c1ccccc1)c1ccccc1)[Si](C)(C)C)(C#[O])C#[O]
• Title of publication: Bimetallic, Spirocyclic, Methylene-Bridged Carbene Complexes of Rhodium and Palladium Derived by Stepwise Metalations of Lithiated Bis(diphenylphosphoranotrimethylsilylimido)methandiide
• Authors of publication: Fang, Min; Jones, Nathan D.; Friesen, Kristina; Lin, Guanyang; Ferguson, Michael J.; McDonald, Robert; Lukowski, Robert; Cavell, Ronald G.
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 6
• Pages of publication: 1652
• a: 9.8074 ± 0.0004 Å
• b: 10.8804 ± 0.0005 Å
• c: 19.6119 ± 0.0009 Å
• α: 75.5998 ± 0.0007°
• β: 76.111 ± 0.0007°
• γ: 77.1069 ± 0.0007°
• Cell volume: 1937.79 ± 0.15 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0231
• Residual factor for significantly intense reflections: 0.021
• Weighted residual factors for significantly intense reflections: 0.0552
• Weighted residual factors for all reflections included in the refinement: 0.0566
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No