Information card for entry 4073968

Structure parameters

• Formula: C32 H45 N5 O W
• Calculated formula: C32 H45 N5 O W
• SMILES: [W]12(N(C(C)C)c3cccc4cccc([N]1(C(C)C)C(=O)N2c1ccc(cc1)C)c34)(=NC(C)(C)C)=NC(C)(C)C
• Title of publication: Bis(imido) W(VI) Complexes Chelated by N,N′-Disubstituted 1,8-Diamidonaphthalene: An Analysis of Bonding, Isocyanate Insertion, and Al-Me Transfer
• Authors of publication: Lavoie, Nathalie; Ong, Tiow-Gan; Gorelsky, Serge I.; Korobkov, Ilia; Yap, Glenn P. A.; Richeson, Darrin S.
• Journal of publication: Organometallics
• Year of publication: 2007
• Journal volume: 26
• Journal issue: 26
• Pages of publication: 6586
• a: 10.7269 ± 0.0014 Å
• b: 17.284 ± 0.003 Å
• c: 18.857 ± 0.003 Å
• α: 67.839 ± 0.008°
• β: 74.348 ± 0.009°
• γ: 76.871 ± 0.015°
• Cell volume: 3086.9 ± 0.9 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0682
• Residual factor for significantly intense reflections: 0.0456
• Weighted residual factors for significantly intense reflections: 0.0857
• Weighted residual factors for all reflections included in the refinement: 0.094
• Goodness-of-fit parameter for all reflections included in the refinement: 1
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No