Information card for entry 4077253

Structure parameters

• Formula: C26 H33 Rh Ru
• Calculated formula: C26 H33 Rh Ru
• SMILES: [Ru]12345678([c]9%10%11[Rh]%12%13%14%15%16%17([c]19([cH]2[cH]3[cH]4%11)[cH]%14[cH]%12[cH]%10%13)[CH]1=[CH]%15CC[CH]%17=[CH]%16CC1)[c]1([c]5([c]8([c]7([c]61C)C)C)C)C
• Title of publication: A New Heterobimetallic Ru,Rh Complex with a Dianionic Pentalene as Bridging Ligand. Synthesis, Crystal Structure, and Catalytic Activity of [Cp*Ru(μ-η5,η3-C8H6)Rh(η4-COD)]
• Authors of publication: Burgos, Francisco; Chávez, Ivonne; Manriquez, Juan M.; Valderrama, Mauricio; Lago, Elena; Molins, Elies; Delpech, Fabien; Castel, Annie; Rivière, Pierre
• Journal of publication: Organometallics
• Year of publication: 2001
• Journal volume: 20
• Journal issue: 7
• Pages of publication: 1287
• a: 14.941 Å
• b: 11.193 Å
• c: 15.035 Å
• α: 90°
• β: 117.63°
• γ: 90°
• Cell volume: 2227.64 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1013
• Residual factor for significantly intense reflections: 0.0476
• Weighted residual factors for significantly intense reflections: 0.1134
• Weighted residual factors for all reflections included in the refinement: 0.1234
• Goodness-of-fit parameter for all reflections included in the refinement: 0.945
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No