Information card for entry 4077355

Structure parameters

• Chemical name: [{MeAs(NHCy)(NCy)}ZnMe]2
• Formula: C28 H58 As2 N4 Zn2
• Calculated formula: C28 H58 As2 N4 Zn2
• SMILES: [As]1([NH](C2CCCCC2)[Zn]2([N]1(C1CCCCC1)[Zn]1([NH](C3CCCCC3)[As]([N]21C1CCCCC1)C)C)C)C
• Title of publication: Methyl Group Transfer from ZnMe2to Arsenic(III), an Alternative Pathway to Deprotonation of [CyNHAs(μ-NCy)]2
• Authors of publication: Bond, Andrew D.; Hopkins, Alexander D.; Rothenberger, Alexander; Wolf, Robert; Woods, Anthony D.; Wright, Dominic S.
• Journal of publication: Organometallics
• Year of publication: 2001
• Journal volume: 20
• Journal issue: 22
• Pages of publication: 4454
• a: 8.1835 ± 0.0005 Å
• b: 9.8676 ± 0.0005 Å
• c: 23.3327 ± 0.0008 Å
• α: 81.031 ± 0.003°
• β: 81.754 ± 0.003°
• γ: 66.919 ± 0.002°
• Cell volume: 1705.1 ± 0.15 ų
• Cell temperature: 180 ± 2 K
• Ambient diffraction temperature: 180 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1049
• Residual factor for significantly intense reflections: 0.0446
• Weighted residual factors for significantly intense reflections: 0.1092
• Weighted residual factors for all reflections included in the refinement: 0.1354
• Goodness-of-fit parameter for all reflections included in the refinement: 1.06
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No