Information card for entry 4078595

Structure parameters

• Formula: C27 H33 N2 P Si
• Calculated formula: C27 H33 N2 P Si
• SMILES: [Si]1(P(c2ccccc2)c2ccccc2)[N](=C(c2ccccc2)N1C(C)(C)C)C(C)(C)C
• Title of publication: Facile Access to the Functionalized N-Donor Stabilized Silylenes PhC(NtBu)2SiX (X = PPh2, NPh2, NCy2, NiPr2, NMe2, N(SiMe3)2, OtBu)
• Authors of publication: Azhakar, Ramachandran; Ghadwal, Rajendra S.; Roesky, Herbert W.; Wolf, Hilke; Stalke, Dietmar
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 12
• Pages of publication: 4588
• a: 8.384 ± 0.003 Å
• b: 9.073 ± 0.003 Å
• c: 17.254 ± 0.004 Å
• α: 89.19 ± 0.01°
• β: 86.06 ± 0.02°
• γ: 72.47 ± 0.01°
• Cell volume: 1248.5 ± 0.7 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0333
• Residual factor for significantly intense reflections: 0.0311
• Weighted residual factors for significantly intense reflections: 0.0828
• Weighted residual factors for all reflections included in the refinement: 0.0841
• Goodness-of-fit parameter for all reflections included in the refinement: 1.061
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No