Information card for entry 4078668

Structure parameters

• Formula: C49 H54 Ir O4 P2 Rh Si3
• Calculated formula: C49 H54 Ir O4 P2 Rh Si3
• Title of publication: Multiple Si‒H Bond Activations in a Bis(diethylphosphino)methane-Bridged Complex of Rhodium and Iridium: Synthesis of an Unusual Bis(silyl)/μ-Silylene Complex
• Authors of publication: Mobarok, Md Hosnay; Ferguson, Michael J.; Cowie, Martin
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 13
• Pages of publication: 4722
• a: 20.6418 ± 0.0009 Å
• b: 10.9486 ± 0.0005 Å
• c: 20.9305 ± 0.0009 Å
• α: 90°
• β: 92.867 ± 0.001°
• γ: 90°
• Cell volume: 4724.3 ± 0.4 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: I 1 2/a 1
• Hall space group symbol: -I 2ya
• Residual factor for all reflections: 0.0197
• Residual factor for significantly intense reflections: 0.0171
• Weighted residual factors for significantly intense reflections: 0.0415
• Weighted residual factors for all reflections included in the refinement: 0.0434
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No