Information card for entry 4079493

Structure parameters

• Formula: C27 H32 Ge N2 O3 Si2 W
• Calculated formula: C27 H32 Ge N2 O3 Si2 W
• SMILES: [Ge]1([W]2345([cH]6[cH]5[cH]4[cH]3[cH]26)(C#[O])(C#[O])C#[O])[n]2ccccc2C([Si](C)(C)C)=C(N1[Si](C)(C)C)c1ccccc1
• Title of publication: Synthesis and Structural Characterization of Metallogermylenes, Cp-Substituted Germylene, and a Germanium(II)-Borane Adduct from Pyridyl-1-azaallyl Germanium(II) Chloride
• Authors of publication: Leung, Wing-Por; Chiu, Wang-Kin; Mak, Thomas C. W.
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 19
• Pages of publication: 6966
• a: 12.853 ± 0.003 Å
• b: 10.569 ± 0.003 Å
• c: 21.936 ± 0.005 Å
• α: 90°
• β: 95.73 ± 0.004°
• γ: 90°
• Cell volume: 2965 ± 1.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0431
• Residual factor for significantly intense reflections: 0.0311
• Weighted residual factors for significantly intense reflections: 0.075
• Weighted residual factors for all reflections included in the refinement: 0.082
• Goodness-of-fit parameter for all reflections included in the refinement: 1.025
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No