Information card for entry 4082430

Structure parameters

• Formula: C23 H11 O11 Os3 Sb
• Calculated formula: C23 H11 O11 Os3 Sb
• SMILES: [Os]1([Os]([OsH]([Sb]1(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O])(C#[O])(C#[O])(C#[O])C#[O])(C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: Oxidative Addition across Sb‒H and Sb‒Sb Bonds by an Osmium Carbonyl Cluster: Trapping the Intermediate
• Authors of publication: Li, Ying-Zhou; Ganguly, Rakesh; Leong, Weng Kee
• Journal of publication: Organometallics
• Year of publication: 2014
• Journal volume: 33
• Journal issue: 3
• Pages of publication: 823
• a: 9.7693 ± 0.0009 Å
• b: 16.097 ± 0.0014 Å
• c: 17.6044 ± 0.0013 Å
• α: 90°
• β: 97.159 ± 0.004°
• γ: 90°
• Cell volume: 2746.8 ± 0.4 ų
• Cell temperature: 103 ± 2 K
• Ambient diffraction temperature: 103 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0371
• Residual factor for significantly intense reflections: 0.0315
• Weighted residual factors for significantly intense reflections: 0.0817
• Weighted residual factors for all reflections included in the refinement: 0.0931
• Goodness-of-fit parameter for all reflections included in the refinement: 1.216
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No