Information card for entry 4082431

Structure parameters

• Formula: C35 H13 Cl2 O22 Os6 Sb
• Calculated formula: C35 H13 Cl2 O22 Os6 Sb
• SMILES: [OsH]1([Os]([Os]1(C#[O])(C#[O])(C#[O])C#[O])(C#[O])(C#[O])(C#[O])C#[O])([Sb]([Os]1([Os]([Os]1(C#[O])(C#[O])(C#[O])C#[O])(C#[O])(C#[O])(C#[O])C#[O])(C#[O])(C#[O])C#[O])(c1ccccc1)c1ccccc1)(C#[O])(C#[O])C#[O].C(Cl)Cl
• Title of publication: Oxidative Addition across Sb‒H and Sb‒Sb Bonds by an Osmium Carbonyl Cluster: Trapping the Intermediate
• Authors of publication: Li, Ying-Zhou; Ganguly, Rakesh; Leong, Weng Kee
• Journal of publication: Organometallics
• Year of publication: 2014
• Journal volume: 33
• Journal issue: 3
• Pages of publication: 823
• a: 9.6091 ± 0.0008 Å
• b: 13.415 ± 0.0012 Å
• c: 19.283 ± 0.0017 Å
• α: 101.276 ± 0.005°
• β: 103.486 ± 0.005°
• γ: 101.811 ± 0.005°
• Cell volume: 2287.4 ± 0.4 ų
• Cell temperature: 103 ± 2 K
• Ambient diffraction temperature: 103 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0717
• Residual factor for significantly intense reflections: 0.0509
• Weighted residual factors for significantly intense reflections: 0.1405
• Weighted residual factors for all reflections included in the refinement: 0.1605
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No