Information card for entry 4084710

Structure parameters

• Formula: C29 H57 N O2 Si5
• Calculated formula: C29 H57 N O2 Si5
• SMILES: [Si]12(O/C(=N/c3c(cccc3C(C)C)C(C)C)O1)C([Si](C)(C)C)([Si](C)(C)C)CCC2([Si](C)(C)C)[Si](C)(C)C
• Title of publication: Reactions of an Isolable Dialkylsilylene with Carbon Dioxide and Related Heterocumulenes
• Authors of publication: Liu, Xupeng; Xiao, Xu-Qiong; Xu, Zheng; Yang, Xuemin; Li, Zhifang; Dong, Zhaowen; Yan, Chenting; Lai, Guoqiao; Kira, Mitsuo
• Journal of publication: Organometallics
• Year of publication: 2014
• Journal volume: 33
• Journal issue: 19
• Pages of publication: 5434
• a: 11.397 ± 0.007 Å
• b: 11.592 ± 0.006 Å
• c: 15.405 ± 0.009 Å
• α: 76.52 ± 0.014°
• β: 70.677 ± 0.011°
• γ: 73.386 ± 0.012°
• Cell volume: 1818.7 ± 1.8 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.069
• Residual factor for significantly intense reflections: 0.0497
• Weighted residual factors for significantly intense reflections: 0.149
• Weighted residual factors for all reflections included in the refinement: 0.1764
• Goodness-of-fit parameter for all reflections included in the refinement: 0.971
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No