Information card for entry 4085729

Structure parameters

• Formula: C38 H44 Cl2 N O4 P Si
• Calculated formula: C38 H44 Cl2 N O4 P Si
• SMILES: P1(=[N]([Si](Cl)(Cl)(C(=C1C(=O)OC)C(=O)OC)C)c1c(cccc1C(C)C)C(C)C)(c1ccccc1)c1ccccc1.c1(ccccc1)C
• Title of publication: Fine Tuning of the Substituents on the N-Geminal Phosphorus/Silicon-Based Lewis Pairs for the Synthesis ofZ-Type Silyliminophosphoranylalkenes
• Authors of publication: Li, Jiancheng; Li, Yan; Purushothaman, Indu; De, Susmita; Li, Bin; Zhu, Hongping; Parameswaran, Pattiyil; Ye, Qingsong; Liu, Weiping
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 17
• Pages of publication: 4209
• a: 9.6383 ± 0.0007 Å
• b: 12.1814 ± 0.0009 Å
• c: 17.9861 ± 0.0014 Å
• α: 70.303 ± 0.007°
• β: 88.249 ± 0.006°
• γ: 68.903 ± 0.007°
• Cell volume: 1845 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0757
• Residual factor for significantly intense reflections: 0.0529
• Weighted residual factors for significantly intense reflections: 0.1162
• Weighted residual factors for all reflections included in the refinement: 0.128
• Goodness-of-fit parameter for all reflections included in the refinement: 1.051
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No