Information card for entry 4086498

Structure parameters

• Formula: C25 H62 N2 Si6 Sm
• Calculated formula: C25 H62 N2 Si6 Sm
• SMILES: [Sm](C([SiH](C)C)([SiH](C)C)[SiH](C)C)(C([SiH](C)C)([SiH](C)C)[SiH](C)C)=C1N(C(C)(C)C)C=CN1C(C)(C)C
• Title of publication: Homoleptic Divalent Dialkyl Lanthanide-Catalyzed Cross-Dehydrocoupling of Silanes and Amines
• Authors of publication: Pindwal, Aradhana; Ellern, Arkady; Sadow, Aaron D.
• Journal of publication: Organometallics
• Year of publication: 2016
• Journal volume: 35
• Journal issue: 11
• Pages of publication: 1674
• a: 11.4634 ± 0.0011 Å
• b: 11.8589 ± 0.0011 Å
• c: 16.2723 ± 0.0015 Å
• α: 72.595 ± 0.001°
• β: 84.882 ± 0.001°
• γ: 62.847 ± 0.001°
• Cell volume: 1875.3 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0259
• Residual factor for significantly intense reflections: 0.0223
• Weighted residual factors for significantly intense reflections: 0.0495
• Weighted residual factors for all reflections included in the refinement: 0.0536
• Goodness-of-fit parameter for all reflections included in the refinement: 1.051
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No