Information card for entry 4100985

Structure parameters

• Formula: C32 H18 O10 P2 W2
• Calculated formula: C32 H18 O10 P2 W2
• SMILES: [W]([P@]1([C@@H]2[P@@]([W](C#[O])(C#[O])(C#[O])(C#[O])C#[O])(C=Cc3c([C@H]12)cccc3)c1ccccc1)c1ccccc1)(C#[O])(C#[O])(C#[O])(C#[O])C#[O].[W]([P@@]1([C@H]2[P@]([W](C#[O])(C#[O])(C#[O])(C#[O])C#[O])(C=Cc3c([C@@H]12)cccc3)c1ccccc1)c1ccccc1)(C#[O])(C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: 3H-Benzophosphepine Complexes: Versatile Phosphinidene Precursors
• Authors of publication: Borst, Mark L. G.; Bulo, Rosa E.; Gibney, Daniele J.; Alem, Yonathan; de Kanter, Franciscus J. J.; Ehlers, Andreas W.; Schakel, Marius; Lutz, Martin; Spek, Anthony L.; Lammertsma, Koop
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2005
• a: 10.4762 ± 0.0001 Å
• b: 11.3603 ± 0.0001 Å
• c: 14.8964 ± 0.0001 Å
• α: 103.56 ± 0.0004°
• β: 99.8561 ± 0.0005°
• γ: 103.982 ± 0.0004°
• Cell volume: 1622.87 ± 0.02 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No