Information card for entry 4100986

Structure parameters

• Formula: C32 H16 Mo2 O10 P2
• Calculated formula: C32 H16 Mo2 O10 P2
• SMILES: [Mo]([P]1(C(c2c(cccc2)C2=C[P]2([Mo](C#[O])(C#[O])(C#[O])(C#[O])C#[O])c2ccccc2)=C1)c1ccccc1)(C#[O])(C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: 3H-Benzophosphepine Complexes: Versatile Phosphinidene Precursors
• Authors of publication: Borst, Mark L. G.; Bulo, Rosa E.; Gibney, Daniele J.; Alem, Yonathan; de Kanter, Franciscus J. J.; Ehlers, Andreas W.; Schakel, Marius; Lutz, Martin; Spek, Anthony L.; Lammertsma, Koop
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2005
• a: 9.2748 ± 0.0004 Å
• b: 12.066 ± 0.0006 Å
• c: 15.2717 ± 0.0006 Å
• α: 90.529 ± 0.002°
• β: 98.06 ± 0.001°
• γ: 104.808 ± 0.002°
• Cell volume: 1634.16 ± 0.12 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No