Information card for entry 4104482

Structure parameters

• Formula: C12 H30 F3 N O3 P2 S Si
• Calculated formula: C12 H30 F3 N O3 P2 S Si
• SMILES: [P+](P(=N[Si](C)(C)C)(C)C)(CC)(CC)CC.S(=O)(=O)([O-])C(F)(F)F
• Title of publication: Synthesis and Reactivity of Phosphine-Stabilized Phosphoranimine Cations, [R3P.PR'2=NSiMe3]+
• Authors of publication: Keith Huynh; Alan J. Lough; Michelle A. M. Forgeron; Martin Bendle; Alejandro Presa Soto; Roderick E. Wasylishen; Ian Manners
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2009
• Journal volume: 131
• Pages of publication: 7905 - 7916
• a: 12.4326 ± 0.0002 Å
• b: 28.4196 ± 0.0007 Å
• c: 36.7682 ± 0.0009 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 12991.3 ± 0.5 ų
• Cell temperature: 150 ± 1 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.1022
• Residual factor for significantly intense reflections: 0.053
• Weighted residual factors for significantly intense reflections: 0.1115
• Weighted residual factors for all reflections included in the refinement: 0.1303
• Goodness-of-fit parameter for all reflections included in the refinement: 1.014
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No