Information card for entry 4113995

Structure parameters

• Common name: (dppe)PtMe4
• Chemical name: (dppe)PtMe4
• Formula: C30 H36 P2 Pt
• Calculated formula: C30 H36 P2 Pt
• SMILES: C[Pt]1(C)(C)(C)[P](CC[P]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Mechanisms of C-C and C-H Alkane Reductive Eliminations from Octahedral Pt(IV): Reaction via Five-Coordinate Intermediates or Direct Elimination?
• Authors of publication: Dawn M. Crumpton-Bregel; Karen I. Goldberg
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2003
• Journal volume: 125
• Pages of publication: 9442 - 9456
• a: 14.6533 ± 0.0002 Å
• b: 11.7535 ± 0.0002 Å
• c: 15.4973 ± 0.0001 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2669.06 ± 0.06 ų
• Cell temperature: 161 ± 2 K
• Ambient diffraction temperature: 161 ± 2 K
• Number of distinct elements: 4
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Residual factor for all reflections: 0.0317
• Residual factor for significantly intense reflections: 0.0302
• Weighted residual factors for significantly intense reflections: 0.0912
• Weighted residual factors for all reflections included in the refinement: 0.0949
• Goodness-of-fit parameter for all reflections included in the refinement: 1.028
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No