Information card for entry 4113996

Structure parameters

• Common name: (dppbz)PtMe4
• Chemical name: (dppbz)PtMe4
• Formula: C34 H36 P2 Pt
• Calculated formula: C34 H36 P2 Pt
• SMILES: C[Pt]1(C)(C)(C)[P](c2ccccc2[P]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Mechanisms of C-C and C-H Alkane Reductive Eliminations from Octahedral Pt(IV): Reaction via Five-Coordinate Intermediates or Direct Elimination?
• Authors of publication: Dawn M. Crumpton-Bregel; Karen I. Goldberg
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2003
• Journal volume: 125
• Pages of publication: 9442 - 9456
• a: 10.0224 ± 0.0004 Å
• b: 11.1025 ± 0.0004 Å
• c: 14.4028 ± 0.0006 Å
• α: 83.39 ± 0.002°
• β: 71.766 ± 0.002°
• γ: 80.506 ± 0.002°
• Cell volume: 1497.88 ± 0.1 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0441
• Residual factor for significantly intense reflections: 0.038
• Weighted residual factors for significantly intense reflections: 0.0868
• Weighted residual factors for all reflections included in the refinement: 0.09
• Goodness-of-fit parameter for all reflections included in the refinement: 1.041
• Diffraction radiation wavelength: 0.71074 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No