Information card for entry 4124369

Structure parameters

• Formula: C27 H42 N4 O2 Si W
• Calculated formula: C27 H42 N4 O2 Si W
• SMILES: [W]1234(C#[O])(C#[O])([c]5([c]1([c]2([c]3([c]45C)C)C)CC)C)[SiH](c1n(c(c([n+]1C)C)C)C)c1n(c(c([n+]1C)C)C)C
• Title of publication: Unexpected Formation of NHC-Stabilized Hydrosilylyne Complexes via Alkane Elimination from NHC-Stabilized Hydrido(alkylsilylene) Complexes.
• Authors of publication: Fukuda, Tetsuya; Hashimoto, Hisako; Tobita, Hiromi
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2015
• Journal volume: 137
• Journal issue: 34
• Pages of publication: 10906 - 10909
• a: 13.01 ± 0.03 Å
• b: 14.11 ± 0.03 Å
• c: 15.26 ± 0.03 Å
• α: 90°
• β: 103.81 ± 0.03°
• γ: 90°
• Cell volume: 2720 ± 10 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0484
• Residual factor for significantly intense reflections: 0.0343
• Weighted residual factors for significantly intense reflections: 0.0612
• Weighted residual factors for all reflections included in the refinement: 0.065
• Goodness-of-fit parameter for all reflections included in the refinement: 1.04
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No