Information card for entry 4124370

Structure parameters

• Formula: C29 H56 N2 O2 Si4 W
• Calculated formula: C29 H56 N2 O2 Si4 W
• SMILES: [WH]1234(C#[O])(C#[O])([c]5([c]4([c]3([c]2([c]15C)C)C)C)C)[SiH](c1n(c(c([n+]1C)C)C)C)C([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C
• Title of publication: Unexpected Formation of NHC-Stabilized Hydrosilylyne Complexes via Alkane Elimination from NHC-Stabilized Hydrido(alkylsilylene) Complexes.
• Authors of publication: Fukuda, Tetsuya; Hashimoto, Hisako; Tobita, Hiromi
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2015
• Journal volume: 137
• Journal issue: 34
• Pages of publication: 10906 - 10909
• a: 9.407 ± 0.001 Å
• b: 11.2192 ± 0.0012 Å
• c: 17.9488 ± 0.0019 Å
• α: 103.741 ± 0.007°
• β: 94.638 ± 0.007°
• γ: 104.367 ± 0.007°
• Cell volume: 1762.8 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0356
• Residual factor for significantly intense reflections: 0.0295
• Weighted residual factors for significantly intense reflections: 0.0524
• Weighted residual factors for all reflections included in the refinement: 0.054
• Goodness-of-fit parameter for all reflections included in the refinement: 1.062
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No