Information card for entry 4127067

Structure parameters

• Formula: C45 H55 F2 O P2 Rh
• Calculated formula: C45 H55 F2 O P2 Rh
• Title of publication: Dehydropolymerization of H3B·NMeH2 To Form Polyaminoboranes Using [Rh(Xantphos-alkyl)] Catalysts.
• Authors of publication: Adams, Gemma M.; Colebatch, Annie L.; Skornia, Joseph T.; McKay, Alasdair I.; Johnson, Heather C.; Lloyd Jones, Guy C.; Macgregor, Stuart A.; Beattie, Nicholas A.; Weller, Andrew S.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2018
• a: 11.9582 ± 0.0005 Å
• b: 14.5158 ± 0.0004 Å
• c: 13.0659 ± 0.0005 Å
• α: 90°
• β: 113.521 ± 0.004°
• γ: 90°
• Cell volume: 2079.58 ± 0.15 ų
• Cell temperature: 150.01 ± 0.1 K
• Ambient diffraction temperature: 150.01 ± 0.1 K
• Number of distinct elements: 6
• Space group number: 11
• Hermann-Mauguin space group symbol: P 1 21/m 1
• Hall space group symbol: -P 2yb
• Residual factor for all reflections: 0.0302
• Residual factor for significantly intense reflections: 0.028
• Weighted residual factors for significantly intense reflections: 0.0716
• Weighted residual factors for all reflections included in the refinement: 0.073
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No