Information card for entry 4301667

Structure parameters

• Formula: C88 H110 Ge2 N2
• Calculated formula: C88 H110 Ge2 N2
• SMILES: c1([Ge]2[NH2][Ge](c3c(cccc3c3c(cccc3C(C)C)C(C)C)c3c(cccc3C(C)C)C(C)C)[NH2]2)c(cccc1c1c(cccc1C(C)C)C(C)C)c1c(cccc1C(C)C)C(C)C.c1(ccccc1)C.c1(C)ccccc1.c1(ccccc1)C.c1(ccccc1)C
• Title of publication: N-H and N=C Bond Formation via Germanium(III) Diradicaloid Intermediates and C-S Bond Cleavage in Reactions of the Digermyne Ar'GeGeAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pri2)2) with Azides
• Authors of publication: Xinping Wang; Chengbao Ni; Zhongliang Zhu; James C. Fettinger; Philip P. Power
• Journal of publication: Inorganic Chemistry
• Year of publication: 2009
• Journal volume: 48
• Pages of publication: 2464 - 2470
• a: 12.0284 ± 0.0009 Å
• b: 13.1937 ± 0.001 Å
• c: 13.6696 ± 0.001 Å
• α: 109.599 ± 0.001°
• β: 102.819 ± 0.001°
• γ: 103.691 ± 0.001°
• Cell volume: 1875 ± 0.2 ų
• Cell temperature: 90 ± 2 K
• Ambient diffraction temperature: 90 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0406
• Residual factor for significantly intense reflections: 0.0352
• Weighted residual factors for significantly intense reflections: 0.0932
• Weighted residual factors for all reflections included in the refinement: 0.0969
• Goodness-of-fit parameter for all reflections included in the refinement: 1.059
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No