Information card for entry 4302311

Structure parameters

• Formula: C13 H32 Br2 Fe N2 P2
• Calculated formula: C13 H32 Br2 Fe N2 P2
• SMILES: [Fe]1(Br)(Br)[P](N(N[P]1(C(C)C)C(C)C)C)(C(C)C)C(C)C
• Title of publication: The First Structurally Characterized Metal (κ^2^N,P)-Phosphinohydrazides: The Key to Understanding the Intramolecular Rearrangement R~2~P‒NR'‒NR'‒M → R'N=PR~2~‒NR'‒M. Metalloderivatives of Diisopropylphosphinohydrazines: Synthesis and Properties
• Authors of publication: Kornev, Alexander N.; Belina, Natalia V.; Sushev, Vyacheslav V.; Fukin, Georgy K.; Baranov, Evgenii V.; Kurskiy, Yuriy A.; Poddelskii, Andrei I.; Abakumov, Gleb A.; Lönnecke, Peter; Hey-Hawkins, Evamarie
• Journal of publication: Inorganic chemistry
• Year of publication: 2009
• Journal volume: 48
• Journal issue: 12
• Pages of publication: 5574 - 5583
• a: 16.6898 ± 0.0005 Å
• b: 10.909 ± 0.0004 Å
• c: 11.6196 ± 0.0004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2115.57 ± 0.12 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Residual factor for all reflections: 0.0434
• Residual factor for significantly intense reflections: 0.0392
• Weighted residual factors for significantly intense reflections: 0.0959
• Weighted residual factors for all reflections included in the refinement: 0.098
• Goodness-of-fit parameter for all reflections included in the refinement: 1.081
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Duplicate of: 4338595
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No