Information card for entry 4302312

Structure parameters

• Formula: C34 H80 Cl6 Co3 N4 O2 P4
• Calculated formula: C34 H80 Cl6 Co3 N4 O2 P4
• SMILES: [Co]123([Cl][Co]4([Cl]1)([Cl]2)[P](N(N[P]4(C(C)C)C(C)C)C)(C(C)C)C(C)C)[P](N(N[P]3(C(C)C)C(C)C)C)(C(C)C)C(C)C.[Co](Cl)(Cl)(Cl)[O]1CCCC1.O1CCCC1
• Title of publication: The First Structurally Characterized Metal (κ^2^N,P)-Phosphinohydrazides: The Key to Understanding the Intramolecular Rearrangement R~2~P‒NR'‒NR'‒M → R'N=PR~2~‒NR'‒M. Metalloderivatives of Diisopropylphosphinohydrazines: Synthesis and Properties
• Authors of publication: Kornev, Alexander N.; Belina, Natalia V.; Sushev, Vyacheslav V.; Fukin, Georgy K.; Baranov, Evgenii V.; Kurskiy, Yuriy A.; Poddelskii, Andrei I.; Abakumov, Gleb A.; Lönnecke, Peter; Hey-Hawkins, Evamarie
• Journal of publication: Inorganic chemistry
• Year of publication: 2009
• Journal volume: 48
• Journal issue: 12
• Pages of publication: 5574 - 5583
• a: 10.082 ± 0.0001 Å
• b: 27.9551 ± 0.0002 Å
• c: 18.4152 ± 0.0003 Å
• α: 90°
• β: 103.442 ± 0.001°
• γ: 90°
• Cell volume: 5048.02 ± 0.1 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0887
• Residual factor for significantly intense reflections: 0.0406
• Weighted residual factors for significantly intense reflections: 0.0891
• Weighted residual factors for all reflections included in the refinement: 0.1041
• Goodness-of-fit parameter for all reflections included in the refinement: 0.968
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Duplicate of: 4338596
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No