Information card for entry 4320959

Structure parameters

• Chemical name: [{1,1,1-tris(diphenylphosphinomethyl)ethane cobalt}(=B5,h3:1-cyclotriphosphorus) (tungsten tetracarbonyl triphenylphosphine)]
• Formula: C65 H58 Cl4 O4 P7 Rh W
• Calculated formula: C65 H58 Cl4 O4 P7 Rh W
• SMILES: [W]([P]12[Rh]345([P](CC(C[P]3(c3ccccc3)c3ccccc3)(C[P]4(c3ccccc3)c3ccccc3)C)(c3ccccc3)c3ccccc3)[P]1[P]25)([P](c1ccccc1)(c1ccccc1)c1ccccc1)(C#[O])(C#[O])(C#[O])C#[O].C(Cl)Cl.C(Cl)Cl
• Title of publication: Cyclotriphosphorus Complexes: Solid-State Structures and Dynamic Behavior of Monoadducts with Carbonyl Fragments
• Authors of publication: Massimo Di Vaira; Markus P. Ehses; Piero Stoppioni
• Journal of publication: Inorganic Chemistry
• Year of publication: 2000
• Journal volume: 39
• Pages of publication: 2199 - 2205
• a: 14.872 ± 0.003 Å
• b: 27.317 ± 0.006 Å
• c: 16.992 ± 0.004 Å
• α: 90°
• β: 111.75 ± 0.05°
• γ: 90°
• Cell volume: 6412 ± 3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0739
• Residual factor for significantly intense reflections: 0.0526
• Weighted residual factors for all reflections: 0.1295
• Weighted residual factors for significantly intense reflections: 0.1228
• Goodness-of-fit parameter for all reflections: 0.92
• Goodness-of-fit parameter for significantly intense reflections: 1.072
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No