Information card for entry 4321772

Structure parameters

• Chemical name: Tetrachloro-tetrakis(bis(dimethylphosphino)methane-P)- -di-molybdenum(II)
• Formula: C20 H56 Cl4 Mo2 P8
• Calculated formula: C20 H56 Cl4 Mo2 P8
• SMILES: C[P](C)(C[P](C)C)[Mo](Cl)([Mo]([P](C)(C)C[P](C)C)([P](C)(C)C[P](C)C)(Cl)Cl)([P](C)(C)C[P](C)C)Cl
• Title of publication: Mixed Chloride/Amine Complexes of Dimolybdenum(II,II). 2. Reactions of Mo2Cl4(NHEt2)4 with Monodentate and Bidentate Phosphines. New Type of Compounds Mo2Cl4(diphosphine)4
• Authors of publication: F. Albert Cotton; Evgeny V. Dikarev; Santiago Herrero
• Journal of publication: Inorganic Chemistry
• Year of publication: 1999
• Journal volume: 38
• Pages of publication: 490 - 495
• a: 12.396 ± 0.001 Å
• b: 12.396 ± 0.001 Å
• c: 21.96 ± 0.002 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 2922.3 ± 0.4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 181
• Hermann-Mauguin space group symbol: P 64 2 2
• Hall space group symbol: P 64 2 (0 0 2)
• Residual factor for all reflections: 0.0373
• Residual factor for significantly intense reflections: 0.0335
• Weighted residual factors for all reflections: 0.0918
• Weighted residual factors for significantly intense reflections: 0.0891
• Goodness-of-fit parameter for all reflections: 1.088
• Goodness-of-fit parameter for significantly intense reflections: 1.096
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No