Information card for entry 4322864

Structure parameters

• Formula: C46 H56 O P6 W
• Calculated formula: C50 H64 O2 P6 W
• Title of publication: Synthesis, Unusual trigonal Prismatic Geometry, and Theoretical Study of the Homoleptic Tris-(2,2'-biphosphinine) Complexes of Chromium, Molybdenum, and Tungsten
• Authors of publication: Patrick Rosa; Louis Ricard; Pascal Le Floch; François Mathey; Gjergji Sini; Odile Eisenstein
• Journal of publication: Inorganic Chemistry
• Year of publication: 1998
• Journal volume: 37
• Pages of publication: 3154 - 3158
• a: 24.815 ± 0.003 Å
• b: 14.7 ± 0.002 Å
• c: 16.754 ± 0.002 Å
• α: 90°
• β: 127.57 ± 0.01°
• γ: 90°
• Cell volume: 4844.1 ± 1.2 ų
• Cell temperature: 123 K
• Ambient diffraction temperature: 123 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.064
• Residual factor for significantly intense reflections: 0.029
• Weighted residual factors for all reflections included in the refinement: 0.037
• Goodness-of-fit parameter for all reflections included in the refinement: 1.002
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: Mo-Kα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No