Information card for entry 4328744

Structure parameters

• Formula: C104 H109 B Ge Ir O6 P4 Rh
• Calculated formula: C96 H93 B Ge Ir O4 P4 Rh
• SMILES: [Ir]123([H][Rh]4([Ge]1(c1ccccc1)(c1ccccc1)[H]4)([P](C[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)([P](C[P]3(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)C#[O])C#[O].c1(ccccc1)[B-](c1ccccc1)(c1ccccc1)c1ccccc1.O1CCCC1.O1CCCC1
• Title of publication: Germyl- and Germylene-Bridged Complexes of Rh/Ir and Subsequent Chemistry of a Bridging Germylene Group
• Authors of publication: Md Hosnay Mobarok; Robert McDonald; Michael J. Ferguson; Martin Cowie
• Journal of publication: Inorganic Chemistry
• Year of publication: 2012
• Journal volume: 51
• Pages of publication: 4020 - 4034
• a: 14.1513 ± 0.0004 Å
• b: 16.7686 ± 0.0005 Å
• c: 20.6792 ± 0.0006 Å
• α: 96.1547 ± 0.0003°
• β: 108.352 ± 0.0003°
• γ: 97.5944 ± 0.0004°
• Cell volume: 4558.6 ± 0.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0307
• Residual factor for significantly intense reflections: 0.0252
• Weighted residual factors for significantly intense reflections: 0.0723
• Weighted residual factors for all reflections included in the refinement: 0.0759
• Goodness-of-fit parameter for all reflections included in the refinement: 1.07
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No