Syntheses and structures of magnesium and zinc boraamidinates: EPR and DFT investigations of Li, Mg, Zn, B, and In complexes of the [PhB(NtBu)2].- anion radical.
Authors of publication
Chivers, Tristram; Eisler, Dana J.; Fedorchuk, Chantall; Schatte, Gabriele; Tuononen, Heikki M.; Boeré, René T
Journal of publication
Inorganic chemistry
Year of publication
2006
Journal volume
45
Journal issue
5
Pages of publication
2119 - 2131
a
10.142 ± 0.002 Å
b
12.481 ± 0.003 Å
c
18.091 ± 0.004 Å
α
89.81 ± 0.03°
β
81.72 ± 0.03°
γ
73.45 ± 0.03°
Cell volume
2170.5 ± 0.9 Å3
Cell temperature
173 ± 2 K
Ambient diffraction temperature
173 ± 2 K
Number of distinct elements
8
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0719
Residual factor for significantly intense reflections
0.0609
Weighted residual factors for significantly intense reflections
0.1548
Weighted residual factors for all reflections included in the refinement
0.1654
Goodness-of-fit parameter for all reflections included in the refinement
