Information card for entry 4340293

Structure parameters

• Formula: C16 H29 Cl2 N2 Rh
• Calculated formula: C16 H29 Cl2 N2 Rh
• SMILES: [Rh]12345(Cl)([NH]=C(C)CC([NH2]1)(C)C)[c]1([c]2([c]3([c]4([c]51C)C)C)C)C.[Cl-]
• Title of publication: The first acetimino complexes of Rh(III). 4-imino-2-methylpentan-2-amino-Rh(III) complexes through metal-assisted intramolecular aldol-type condensation of two acetimino ligands.
• Authors of publication: Vicente, José; Chicote, María-Teresa; Guerrero, Rita; Vicente-Hernández, Inmaculada; Alvarez-Falcón, Miguel M
• Journal of publication: Inorganic chemistry
• Year of publication: 2006
• Journal volume: 45
• Journal issue: 1
• Pages of publication: 181 - 188
• a: 13.5331 ± 0.0006 Å
• b: 12.037 ± 0.0004 Å
• c: 22.7027 ± 0.0008 Å
• α: 90°
• β: 94.644 ± 0.004°
• γ: 90°
• Cell volume: 3686.1 ± 0.2 ų
• Cell temperature: 133 ± 2 K
• Ambient diffraction temperature: 133 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0397
• Residual factor for significantly intense reflections: 0.0262
• Weighted residual factors for significantly intense reflections: 0.0559
• Weighted residual factors for all reflections included in the refinement: 0.0607
• Goodness-of-fit parameter for all reflections included in the refinement: 1.052
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No