Information card for entry 4340294

Structure parameters

• Formula: C16 H29 Cl2 N2 O4 Rh
• Calculated formula: C16 H29 Cl2 N2 O4 Rh
• SMILES: [Rh]1234(Cl)([NH]=C(C)C)([NH]=C(C)C)[c]5([c]1([c]2([c]3([c]45C)C)C)C)C.Cl(=O)(=O)(=O)[O-]
• Title of publication: The first acetimino complexes of Rh(III). 4-imino-2-methylpentan-2-amino-Rh(III) complexes through metal-assisted intramolecular aldol-type condensation of two acetimino ligands.
• Authors of publication: Vicente, José; Chicote, María-Teresa; Guerrero, Rita; Vicente-Hernández, Inmaculada; Alvarez-Falcón, Miguel M
• Journal of publication: Inorganic chemistry
• Year of publication: 2006
• Journal volume: 45
• Journal issue: 1
• Pages of publication: 181 - 188
• a: 8.5542 ± 0.0003 Å
• b: 15.911 ± 0.0006 Å
• c: 15.4317 ± 0.0006 Å
• α: 90°
• β: 102.138 ± 0.001°
• γ: 90°
• Cell volume: 2053.39 ± 0.13 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0193
• Residual factor for significantly intense reflections: 0.0189
• Weighted residual factors for significantly intense reflections: 0.0471
• Weighted residual factors for all reflections included in the refinement: 0.0473
• Goodness-of-fit parameter for all reflections included in the refinement: 1.065
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No