Information card for entry 4344678

Structure parameters

• Formula: C35 H61 N3 Si2 Sm
• Calculated formula: C35 H61 N3 Si2 Sm
• SMILES: [Sm]123456(N([Si](C)(C)C)[Si](C)(C)C)N(C(=N[c]73[c]4([cH]5[cH]6[cH]2[c]71C(C)C)C(C)C)C(C)(C)C)c1c(cccc1C(C)C)C(C)C
• Title of publication: Amido Ln(II) Complexes Coordinated by Bi- and Tridentate Amidinate Ligands: Nonconventional Coordination Modes of Amidinate Ligands and Catalytic Activity in Intermolecular Hydrophosphination of Styrenes and Tolane.
• Authors of publication: Basalov, Ivan V.; Yurova, Olga S.; Cherkasov, Anton V.; Fukin, Georgy K.; Trifonov, Alexander A.
• Journal of publication: Inorganic chemistry
• Year of publication: 2016
• Journal volume: 55
• Journal issue: 3
• Pages of publication: 1236 - 1244
• a: 18.2022 ± 0.0013 Å
• b: 12.1697 ± 0.0009 Å
• c: 16.9441 ± 0.0013 Å
• α: 90°
• β: 99.999 ± 0.002°
• γ: 90°
• Cell volume: 3696.4 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0417
• Residual factor for significantly intense reflections: 0.0324
• Weighted residual factors for significantly intense reflections: 0.0811
• Weighted residual factors for all reflections included in the refinement: 0.0844
• Goodness-of-fit parameter for all reflections included in the refinement: 0.991
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No