Information card for entry 4348666

Structure parameters

• Formula: C58 H80 Cl N3 P Rh Si2
• Calculated formula: C58 H80 Cl N3 P Rh Si2
• Title of publication: Silacyclopropylideneplatinum(0) Complex as a Robust and Efficient Hydrosilylation Catalyst.
• Authors of publication: Troadec, Thibault; Prades, Amparo; Rodriguez, Ricardo; Mirgalet, Raphael; Baceiredo, Antoine; Saffon-Merceron, Nathalie; Branchadell, Vicenç; Kato, Tsuyoshi
• Journal of publication: Inorganic chemistry
• Year of publication: 2016
• Journal volume: 55
• Journal issue: 16
• Pages of publication: 8234 - 8240
• a: 19.664 ± 0.0011 Å
• b: 18.895 ± 0.001 Å
• c: 14.6049 ± 0.0008 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5426.5 ± 0.5 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 7
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Residual factor for all reflections: 0.1324
• Residual factor for significantly intense reflections: 0.0533
• Weighted residual factors for significantly intense reflections: 0.0773
• Weighted residual factors for all reflections included in the refinement: 0.0955
• Goodness-of-fit parameter for all reflections included in the refinement: 0.998
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No