Information card for entry 4348667

Structure parameters

• Formula: C44 H62 Cl3 Cu N3 P Si2
• Calculated formula: C44 H62 Cl3 Cu N3 P Si2
• Title of publication: Silacyclopropylideneplatinum(0) Complex as a Robust and Efficient Hydrosilylation Catalyst.
• Authors of publication: Troadec, Thibault; Prades, Amparo; Rodriguez, Ricardo; Mirgalet, Raphael; Baceiredo, Antoine; Saffon-Merceron, Nathalie; Branchadell, Vicenç; Kato, Tsuyoshi
• Journal of publication: Inorganic chemistry
• Year of publication: 2016
• Journal volume: 55
• Journal issue: 16
• Pages of publication: 8234 - 8240
• a: 41.148 ± 0.005 Å
• b: 10.4786 ± 0.0014 Å
• c: 22.226 ± 0.003 Å
• α: 90°
• β: 103.36 ± 0.006°
• γ: 90°
• Cell volume: 9324 ± 2 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1512
• Residual factor for significantly intense reflections: 0.06
• Weighted residual factors for significantly intense reflections: 0.1156
• Weighted residual factors for all reflections included in the refinement: 0.1445
• Goodness-of-fit parameter for all reflections included in the refinement: 1.011
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No