Information card for entry 7001769

Structure parameters

• Formula: C51.38 H44.75 Cl2.75 Ir2 Mo O4 P4 S2
• Calculated formula: C51.38 H42 Cl2.75 Ir2 Mo O4 P4 S2
• Title of publication: Preparation of a bis(hydrosulfido) complex of Mo having a tetraphosphine co-ligand and its transformation into MoRh2 and MoIr2 mixed-metal sulfido clusters
• Authors of publication: Iwasa, Kentaro; Seino, Hidetake; Niikura, Fumiya; Mizobe, Yasushi
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 31
• Pages of publication: 6134
• a: 41.213 ± 0.009 Å
• b: 12.066 ± 0.002 Å
• c: 21.619 ± 0.004 Å
• α: 90°
• β: 95.8523 ± 0.001°
• γ: 90°
• Cell volume: 10695 ± 4 ų
• Cell temperature: 293.1 K
• Number of distinct elements: 8
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for significantly intense reflections: 0.049
• Weighted residual factors for all reflections included in the refinement: 0.177
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No