Information card for entry 7001768

Structure parameters

• Formula: C50.5 H43 Cl Mo O4 P4 Rh2 S2
• Calculated formula: C50.5 H43 Cl Mo O4 P4 Rh2 S2
• Title of publication: Preparation of a bis(hydrosulfido) complex of Mo having a tetraphosphine co-ligand and its transformation into MoRh2 and MoIr2 mixed-metal sulfido clusters
• Authors of publication: Iwasa, Kentaro; Seino, Hidetake; Niikura, Fumiya; Mizobe, Yasushi
• Journal of publication: Dalton Transactions
• Year of publication: 2009
• Journal issue: 31
• Pages of publication: 6134
• a: 13.709 ± 0.004 Å
• b: 17.143 ± 0.004 Å
• c: 20.98 ± 0.005 Å
• α: 90°
• β: 101.07 ± 0.0013°
• γ: 90°
• Cell volume: 4839 ± 2 ų
• Cell temperature: 293.1 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 0.063
• Weighted residual factors for all reflections included in the refinement: 0.201
• Goodness-of-fit parameter for all reflections included in the refinement: 1.077
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No