Information card for entry 7007694

Structure parameters

• Formula: C75 H56 O20 P4 Pt2 Ru6
• Calculated formula: C75 H56 O20 P4 Pt2 Ru6
• SMILES: [Pt]12([Pt]([P](C[P]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)([P](C[P]2(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)C#[O])C#[O].[Ru]123456([Ru]789([Ru]%10%111([Ru]1%122([Ru]2%1337([Ru]8%101(C#[O])(C#[O])(C2=O)[C]69%11%12%13)(C#[O])C#[O])(C5=O)(C#[O])C#[O])(C#[O])(C#[O])C#[O])(C4=O)(C#[O])C#[O])(C#[O])C#[O].O=C(C)C.O=C(C)C
• Title of publication: Synthesis of nonanuclear heterometallic carbide clusters. Unexpected formation of the [Ru6(CO)16]2-[Pt2(CO)2(dppm)2]2+ ion pair on the way to [Ru6C(CO)16Pt3(dppm)2].
• Authors of publication: Koshevoy, Igor O.; Haukka, Matti; Pakkanen, Tapani A.; Tunik, Sergey P.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2006
• Journal issue: 47
• Pages of publication: 5641 - 5647
• a: 13.2584 ± 0.0002 Å
• b: 15.6025 ± 0.0004 Å
• c: 37.266 ± 0.001 Å
• α: 88.171 ± 0.001°
• β: 87.83 ± 0.002°
• γ: 83.907 ± 0.002°
• Cell volume: 7656.9 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0877
• Residual factor for significantly intense reflections: 0.0518
• Weighted residual factors for significantly intense reflections: 0.0896
• Weighted residual factors for all reflections included in the refinement: 0.0983
• Goodness-of-fit parameter for all reflections included in the refinement: 1.109
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No