Information card for entry 7008513

Structure parameters

• Formula: C25 H10 O17 Os5 Rh2
• Calculated formula: C25 H10 O17 Os5 Rh2
• SMILES: [Os]12345([Os]678([Os]9%10([Os]16([Os]27(C#[O])(C#[O])C#[O])([Rh]39([Rh]1236748%10[cH]4[c]1([cH]2[c]3([cH]6[cH]74)C)C)(C#[O])(C#[O])C5=O)(C#[O])(C#[O])C#[O])(C#[O])(C#[O])C#[O])(C#[O])(C#[O])C#[O])(C#[O])C#[O]
• Title of publication: Synthesis and structural characterization of a series of high-hydride content osmium-rhodium carbonyl complexes by the hydrogenation of arene-coordinated clusters.
• Authors of publication: Lau, Jasmine Po-Kwan; Wong, Wing-Tak
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2005
• Journal issue: 15
• Pages of publication: 2579 - 2587
• a: 9.503 ± 0.002 Å
• b: 10.726 ± 0.002 Å
• c: 18.029 ± 0.003 Å
• α: 89.28 ± 0.01°
• β: 76.51 ± 0.01°
• γ: 67.26 ± 0.01°
• Cell volume: 1641.9 ± 0.6 ų
• Cell temperature: 298 ± 1 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.04
• Weighted residual factors for all reflections included in the refinement: 0.042
• Goodness-of-fit parameter for all reflections included in the refinement: 1.103
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No